Limonene (Lim)

Limonene is a colourless liquid hydrocarbon classified as a cyclic terpene. The more common D-isomer possesses a strong smell of oranges. It is used in chemical synthesis as a precursor to carvone and as a renewably based solvent in cleaning products. Limonene takes its name from the lemon, as the rind of the lemon, like other citrus fruits, contains considerable amounts of this compound, which contributes to their odor. Limonene is a chiral molecule, and biological sources produce one enantiomer: the principal industrial source, citrus fruit, contains D-limonene ((+)-limonene), which is the (R)-enantiomer. Limonene is a relatively stable terpene and can be distilled without decomposition, although at elevated temperatures it cracks to form isoprene. It oxidizes easily in moist air to produce carveol, carvone, and limonene oxide.[4] With sulfur, it undergoes dehydrogenation to p-cymene.